Abstract:
The declining state of soil fertility and productivity in Ethiopia can be attributed to the 
inadequate attention given to the biological, chemical, and physical properties of soil. 
Additionally, the high phosphorus fixing characteristics of Vertisols have posed a significant 
challenge to agriculture in the country, leading to phosphorus deficiency, and rendering 
inorganic fertilizers less effective. Greenhouse and field experiments were conducted at 
Haramaya University, eastern Ethiopia, to investigate the effect of mixed manure rates (0, 5, 
10, and 15 t ha-1
), blended nitrogen, phosphorus, sulfur, and boron (NPSB) fertilizer rates (0, 
50, 100, and 150 kg ha-1
), and cropping systems (maize monocropping and maize faba bean 
intercropping) when used alone or in combination on selected soil chemical properties, 
phosphorus adsorption and desorption characteristics, and performance and nutrient uptake 
of maize (Zea mays L.) in Vertisols. Five experiments were conducted. Relevant soil and crop 
data were collected from all the experiments and subjected to statistical analysis. The results 
of the first experiment revealed that the application of mixed manure significantly decreased 
the soil pH, calcium carbonate content, the amount and efficiency of adsorbed phosphorus, 
and the Freundlich adsorption coefficient and constant while increasing available P and 
percentage of desorbed P. The highest changes in these parameters were observed in the 
treatment that received 15 t ha–1 of mixed manure. The findings of the second and third 
experiments demonstrated a significant reduction in soil pH, phosphorus adsorption 
efficiency, Freundlich adsorption coefficient and constant (p ≤ 0.001), and also an increase 
in organic carbon, total nitrogen, and available phosphorus. Moreover, significant 
improvements were observed in the growth parameters of maize plants, including height and 
diameter, tissue nitrogen and phosphorus content and uptake, and total above-ground 
biomass. The highest improvement in the majority of these parameters was observed for the 
combined use of 15 t ha–1
of mixed manure and 100 kg ha–1
of blended NPSB fertilizer 
compared to the control as well as their sole application. The findings of the fourth experiment 
also showed that the quantities of adsorbed phosphorus in all treatments revealed an 
increasing trend with an increased rate of added P concentration from 100 to 500 mg kg−1
. 
However, the efficiency of adsorbed P decreased significantly as added P concentration rates 
increased from 100 to 400 mg kg−1 in all the treatments, and then decreased as the added 
phosphorus concentration advanced to 500 mg kg−1. Moreover, all treatments that received 
mixed manure and blended NPSB combined applications showed a significant increase in 
both quantity and percentage of desorbed P compared to the control. The Freundlich 
adsorption coefficient and constant were also significantly reduced because of the combined 
application of mixed manure and blended NPSB. Overall, the soil treated with a combined 
application of 15 t ha−1 of MM with 100 kg ha−1 of blended NPSB showed the highest 
reduction in both quantity and efficiency of adsorbed phosphorus, as well as Freundlich 
adsorption coefficient and constant while increasing the quantity and percentage of desorbed 
P. The findings of the fifth experiment indicated that intercropping maize with faba bean led 
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to a noteworthy reduction in soil pH, but significantly increased soil organic carbon. 
Similarly, the interaction of the cropping system and blended NPSB also revealed the highest 
value of soil total nitrogen in maize-faba bean intercropping with 150 kg ha−1 NPSB 
suggesting its ability to augment belowground biomass. However, available phosphorus was 
higher in maize monocropping with 150 kg ha−1 NPSB. The cropping system and blended 
NPSB were found to have a significant influence on maize plant height, diameter, above ground biomass, total nitrogen, and phosphorus uptake. The interaction effects of the 
cropping system and blended NPSB revealed higher total nitrogen and phosphorus uptake of 
maize including nitrogen content in monocropped maize with 150 kg ha−1 NPSB. In 
conclusion, intercropping maize and faba bean, along with blended NPSB fertilizer, could be 
a promising approach to improving soil fertility. However, for enhanced crop productivity, 
maize growth parameters and nutrient uptake require further investigation, particularly in 
reducing competition for light, water, and other nutrients. Therefore, it is recommended that 
further research be conducted to evaluate the long-term effects of combined application of 
mixed manure, blended NPSB, and cropping system on soil fertility and nutrient uptake of 
different maize varieties.